Therefore, we are reporting the comparative sensing behavior of intrinsic PANI and GR/PANI nanocomposite film towards toluene gas. For this, the polymer nanocomposite films are grown using spin coating. In order to compare the sensing behavior of nanocomposite PANI films with homogeneous PANI films, the PANI based sensors are also fabricated following the similar technique. The films are characterized using scanning electron microscopy (SEM) as well as Fourier transform infrared spectroscopy (FTIR) and later are analyzed at different operating temperature for the sensing of 100 ppm toluene.2.?Experimental Section2.1. Fabrication of PANI and C-PANI Based SensorThe PANI (emeraldine salt; Sigma Aldrich, St.
Louis, MO, USA) is first converted into the base form by treating it with ammonia (NH4OH) solution and later dissolved in N-methyl-2-pyrrolidone (NMP; Sigma Aldrich) by a combined magnetic stirring and sonication process. After dissolving the PANI in NMP, the solution is divided into two parts. To one of the parts, graphene is added to make graphene-PANI in 1:2 ratio. The nanocomposite PANI-NMP solution is further stirred magnetically and sonicated (at 200 watt for 6 h) to uniformly disperse the graphene flacks. The homogeneous PANI-NMP solution and nanocomposite PANI-NMP (i.e., GR-PANI-NMP) solution are tagged as Sol1 and Sol2 respectively. The films of these solutions are spin coated layer-by-layer (LbL) on piranha-cleaned SiO2-coated Si substrates. In order t
Crustaceans such as crabs, lobsters and crayfish use chemo- and mechano-reception to track sources of odorant plumes to locate mates, food, and living habitat [1�C6].
Odorants in the benthic flow are carried to the olfactory organs of the animal through turbulent water currents and diffuse toward the surface of the organs where chemoreceptors are located. These olfactory organs also contain mechano-receptors that provide information about the turbulent flow, and together with odorant concentration help the animal locate the source of the chemical plume [7]. Animals use a variety of sensing strategies to orient themselves in the direction of the plume source depending on the flow regimes they operate in [8]. Hence, to understand the mechanism of chemical plume tracking in aquatic animals, we must understand not only the small scale diffusive flow Anacetrapib of odorants near the olfactory organs of the animals, but also the large scale turbulent nature of the chemical plume.
Crustaceans have olfactory appendages called antennules, which bear tiny hair-like structures called aesthetascs (Figure 1). The aesthetascs are often covered by a permeable cuticle membrane underneath which reside chemoreceptors. The chemoreceptors contained on the aesthetascs are composed of dendrites (branched projections) of olfactory receptor neurons (ORNs), which send information, through electrical impulses, to the olfactory lobes of the brain [9].